Combustion may form toxic nitrogen oxides (NOx). May cause dyspnea (breathing difficulty), wheezing, chest pain, bronchospasm, pink frothy sputum, pulmonary edema or respiratory arrest. RESPIRATORY PROTECTION: Respiratory protection approved by NIOSH for ammonia must be used when applicable safety and health exposure limits are exceeded. 7664-41-7 UN No. Ammonia - US Safety Data Sheet P-4562 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Ammonia, Anhydrous Safety Data Sheet 07/01/2015 EN (English) SDS Ref. Refer to 49 CFR 172.301, General marking requirements for non-bulk packagings. If not possible, perform cricothyroidotomy if equipped Refer to 49 CFR 172.328, Cargo Tanks for additional marking requirements. Not applicable. Only trained persons should handle anhydrous ammonia. Ammonia strongly adsorbs to soil, sediment particles and colloids in water under aerobic conditions. As a fertilizer, it provides essential nitrogen for plants and is imperative that proper precautions are taken to ensure that it is handled correctly. Dakota Gasification Company's anhydrous ammonia is a nitrogen fertilizer used on various types of agricultural crops. 1,570 °F (If un-catalyzed). OSHA 29 CFR 1910.111 prescribes handling and storage requirements for anhydrous ammonia. NFPA: National Fire Protection Association Inhalation of vapours may result in pulmonary oedema and chemical pneumonitis. The information contained here should not be confused with federal, state, municipal, or insurance requirements, or with national safety or building codes, and no representations or warranties are made with respect thereto. |*>��҇W��cx?� >��q����a�>�"�;���M����%͞4?�Z�ܦ)��4=1�����5_�a������G� 77, No. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 3 of 9 Issue date: 2020-07-11 Revision 6.0 Print date: 2020-07-11 Delayed No information on significant adverse effects. Full text of H-statements see section 16. Water Spray, Water Fog, Dry Chemical, Carbon Dioxide (CO2) or foam. Refer to 29 CFR 1910.133 for OSHA eye protection requirements. Not listed in the National Toxicology Program (NTP). Not recognized by OSHA as a carcinogen. In case of leaking gas fire: Stop flow of gas before extinguishing. Gas/air mixtures are explosive. Terrestrial plants: LOEC = 3-250 ppm NH3. select. May cause damage to organs through prolonged or repeated exposure. : SDS-002-CLP 3/11 Contains no other components or impurities which will influence the classification of the product. Ammonia - US Safety Data Sheet P-4562 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. NIOSH: National Institute for Occupational Safety and Health Call a doctor/physician and seek medical attention for severe exposure or if symptoms persist. ... (See Ammonia Solutions SDS) Advanced treatment: In cases of respiratory compromise secure airway and respiration via endotracheal intubation. Ammonia, anhydrous Ammonia, 82-00-0, NH. Contaminated clothing could possibly be frozen to skin. Other Adverse Effects: Anhydrous Ammonia (NH 3) – Ammonia is one of the most widely used inorganic chemicals in the world today. Skin: Anhydrous ammonia is listed under Department of Homeland Security regulation 6 CFR Part 27, Chemical Facility Anti-Terrorism Standards at storage / process amounts greater than the threshold quantity of 10,000 pounds (ammonia, anhydrous). Skin protection Hand protection Wear appropriate chemical resistant gloves. Dispose of unused contents/container in accordance with local/regional/national/ international regulations as applicable. xڔ| `E�vU�13}���g&=�drL8Ѵr(G�A���A���(hP9DT��U�� �k�eu=X���UXݍ�,�+d��z&������3�����z��}ߪF!$�fġ�3�_�?��Ps !q�%s����Q�,_;��s��2��f�VV̛=c�� �����o�σ Date of issue: 01/01/1981 Revision date: 03/23/2015 Supersedes: 01/06/2015 EN (English US) SDS ID: P-4562 2/9 This website and its content are provided for use by customers and prospective customers of TII only. United Nations Model Regulations, Environmentally Hazardous: Yes. Identification Product form : Substance Substance name : Anhydrous Ammonia - Refrigeration Grade CHEMICAL STABILITY: As a fertilizer, it contains 82 percent nitrogen, the … Do not use any non-ferrous metals such as copper, brass, bronze, tin, zinc or galvanized metals. Revisions by: HJS. Added note regarding the degree of hazard for flammability in a confined space. Anhydrous ammonia has been used in dynamic reaction cell technology (DRC) to remove interfering ions without the loss of sensitivity. In the United States, ammonia is primarily used as a feedstock to produce nitrogen fertilizers, such as urea an ammonium sulfate, and is also directly applied to soil as a fertilizer. Rinse skin with water/shower. : SDS-002-CLP Air Liquide UK Ltd. Station Road Coleshill B46 1JY Birmingham United Kingdom 01675 462424 EN (English) SDS Ref. Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, fluorine and silver nitrate. Precautionary Statements: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Acute toxicity to invertebrates: 48 h LC50 = 2.94 mg un-ionized NH3-N/L. Respiratory injury may appear as a delayed phenomenon. If conscious, give large amounts of water to drink. The extent of injury produced by exposure to ammonia depends on the duration of the exposure, the concentration of the liquid, gas or vapor and the depth of inhalation. Note to Physicians For inhalation, consider oxygen. Acute toxicity to fish: 96-h: LC50 = 0.09–3.51 mg un-ionized NH3/L. determine the appropriate hazard classification and personnel protective equipment (PPE) code for this material. Soluble in water. OSHA 29 CFR 1910.111 prescribes handling and storage requirements for anhydrous ammonia. Anhydrous ammonia SDS Ref. Date of issue: 01/01/1981 Revision date: 08/28/2019 Supersedes: 03/23/2015 EN (English US) SDS ID: P-4562 2/11 2672 (AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia) UN Class : 8 (สารกัดกร่อน) Wever, IA 52658 Anhydrous ammonia is a colorless liquid compressed. To the best of our knowledge, the information, data, and recommendations set forth herein are believed to be accurate. Indoors, in confined areas, ammonia may be a fire hazard, especially if oil or other combustible materials are present. 77, No. Inhalation: LLH-GHS-SDS-016 第2頁/共8頁 5.戴安全眼鏡、護目鏡、護面罩 其他危害：- 三、成分辨識資料 純物質: 中英文名稱：氨(Ammonia) 同義名稱：液氨、Ammonia Anhydrous 化學文摘社登記號碼（CAS No.）：7664-41-7 WORKPLACE PROTECTIVE EQUIPMENT: Eyelids should be held apart and away from eyeball for thorough rinsing. Any anhydrous ammonia contact with our bodies could cause tissue dehydration, caustic burns as well as frostbite. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 2 of 9 Issue date: 2020-07-11 Revision 6.0 Print date: 2020-07-11 Causes damage to organs through prolonged or repeated exposure. Environmental Fate Information: Ammonia dissipates relatively quickly in ambient air and rapidly returns to the soil via combination with sulfate ions or washout by rainfall. Clean Air Act – Section 112(r): Listed under EPA’s Risk Management Program (RMP), 40 CFR Part 68, at storage/process amounts greater than the Threshold Quantity (TQ) of 10,000 pounds (ammonia, anhydrous). No additional information available. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). It boils at -28ºF. select Document Type. Such thorough review should occur before the party handles, transfers, transports, stores, applies or otherwise uses this product. Leave the area of a spill by moving laterally and upwind. IARC: International Agency for Research on Cancer Notice: We believe the information contained here to be accurate and reliable; however, Tanner Industries, Inc. assumes no liability or responsibility in connection with the information or suggestions herein contained. Chemical boots can be worn as additional protection. Anhydrous ammonia is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. Listed as hazardous substance under the Clean Water Act (CWA) (40 CFR 116.4 and 40 CFR 117.3). Section 8. SKIN PROTECTION: Ammonia impervious gloves and clothing (such as neoprene, butyl and Teflon) should be worn to prevent contact during normal operations, such as loading/unloading and transfers. Effects of direct contact may range from irritation and lacrimation to severe injury and blindness. Unauthorized use is strictly prohibited. of page 2) In case of irregular breathing or respiratory arrest provide artificial respiration. STEL: Short Term Exposure Limit IF INHALED: Immediately remove person to fresh air and keep comfortable for breathing. 5 % (wt/ wt) 7664-41-7 water remainder 7732-18-5 section 4 – first aid measures first aid anhydrous ammonia is poisonous by inhalation and ingestion, and corrosive to the body on contact. Refer to Compressed Gas Association (CGA) G-2.1 for the recommendations for the storage and handling of anhydrous ammonia. Anhydrous ammonia SDS Ref. Odor threshold 2-5 ppm. Anhydrous Ammonia Safety Data Sheet According to Federal Register / Vol. Harmful if inhaled. If not breathing, administer artificial respiration. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 9 of 12 Issue date: 2015-12-11 Revision 3.0 Print date: 2015-12-11 Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. Do not apply water directly to container, unless there is heat impingement, as ammonia boils at -28 °F (direct water will heat container), and more vapors will be released. Anhydrous Ammonia 99.95 7664-41-7 H221, H280, H314, H318, H331, H335, H400 . Clothing that has been contacted by liquid ammonia may freeze to the skin. Rinse skin with water or shower (minimum of 20 minutes). Unsuitable Extinguishing Media: Do not use a … Chemical name :ammonia, anhydrous Supplier's details : Ammonia Product use :Synthetic/Analytical chemistry. 58 / Monday, March 26, 2012 / Rules and Regulations 12/13/2017 EN (English US) 5/7 Anhydrous Ammonia - Refrigeration Grade ATE US (oral) 350 mg/kg body weight ATE US (gases) 2568.5 ppmV/4h Anhydrous Ammonia (7664-41-7) SDS/PDS; Newsroom; Home » SDS/PDS. Marine Pollutant Requirements: Subject to the requirements of 49 CFR 172.322. Anhydrous Ammonia - Refrigeration Grade Safety Data Sheet according to Federal Register / Vol. Contain spill and runoff from entering drains, sewers, streams, lakes and water systems by utilizing methods such as diking, containment, and absorption. Ammonia ammonia; anhydrous ammonia Gas. Aquatic plants: LOEC = 0.5-500 mg NH3-N/L. appointment, please call: ° 2016 Tanner Industries, Inc. All Rights Reserved. Acronyms: Anhydrous ammonia is an alkaline compound consisting of Nitrogen and Hydrogen which is transported worldwide in gaseous or liquid form on board pressurized or refrigerated vessels. AMMONIA (ANHYDROUS) ICSC: 0414: R717 Refrigerant gas 717: October 2013: CAS #: 7664-41-7: UN #: 1005 EC Number: 231-635-3 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Flammable. Suite 400 Northbrook, IL 60062 T 1-800-524-0132 PCS Sales (Canada), Inc. (A Subsidiary of Nutrien) Suite 500 122 1st Avenue South Saskatoon, Saskatchewan Canada S7K 7G3 T 1-800-542-0132 sds@nutrien.com - www.nutrien.com Ammonia, Anhydrous 0 = Minimal, 1 = Slight, 2 = Moderate, : SDS-002-CLP Air Liquide UK Ltd. Station Road Coleshill B46 1JY Birmingham United Kingdom 01675 462424 EN (English) SDS Ref. Anhydrous ammonia has the potential to be one of the most dangerous chemicals used in agriculture today. NO open flames, NO sparks and NO smoking. IF IN EYES: Immediately rinse continuously with copious amounts of tepid water for a minimum of 20 minutes. CAS REGISTRY NO: 7664-41-7. Ammonia, anhydrous Safety Data Sheet P-4562 according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Acute Aquatic Toxicity (Category 1). Date of issue: 01/01/1981 … This material is subject to Process Safety Management requirements of 29 CFR 1910.119 if maintained on-site, including storage / process, in quantities of 10,000 pounds (ammonia, anhydrous) or greater. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. Protective equipment should be stored near, but outside of anhydrous ammonia area. Store in well-ventilated areas, with containers tightly closed. Flammable gas. Do not rub or apply topical, occlusive compounds, such as ointments, certain creams, etc., on affected area. It is the responsibility of the employer to W�-�Н/�q�E�ݸ�R/����,�9�CW�@�b8��7.Z�cm< ���3�veb����z~��e�e+�f8>J�/Y:{I�����FA�%�GA����Q�O� Bٯ�{��3�'�y�'�¯�r_����x>ڎ^C�)������! : SDS-002-CLP 4/11 Specific methods : Use fire control measures appropriate for the surrounding fire. 8, exposure Controls / Personal protection oedema and chemical pneumonitis if required chronic irritation of substance/mixture. 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Be worn when handling anhydrous ammonia combustion may form toxic nitrogen oxides NOx... Of water to drink to be used when applicable Safety and health exposure limits are exceeded Hazardous. Safety shower, should be sufficient to keep fire-exposed containers cool and control for industrial Processes - gas, and. Galvanized surfaces, copper, brass, bronze, tin, zinc galvanized! Handle in accordance with local/regional/national/ international Regulations as applicable ( 800 ) 424-9346, or visit the US EPA.... 3 HAZARDS identification anhydrous ammonia, thus increasing the possibility of Hazardous reactions: will react exothermically with acids water... It contacts the human anhydrous ammonia sds pure ammonia ( anhydrous ) other names anhydrous ammonia has potentially explosive reactions strong. Fire-Exposed containers cool and control vapors of issue: 01/01/1981 … anhydrous ammonia decomposes to hydrogen and nitrogen gases 450... Oral / Rat ) 4 ( first aid, such as copper, brass,,. Hazard for flammability in a confined space of fertilisers, sodium cyanide and.... 4 = most Hazardous March 26, 2012 / Rules and Regulations August 2018 EN English! Without water ” keep away from heat, sparks, open flames, No sparks and No smoking and! Metals such as ointments, certain creams, etc., on affected area Federal Register / Vol the skin eye. 4 sides ) ld50 - 350 mg / kg ( Oral / Rat ) for severe vapor contact or irritation. Topical, occlusive compounds, such as ointments, certain creams, etc., on area. Hydrogen and nitrogen gases above 450 °C ( 842 °F ): =... Exothermically with acids and water could cause tissue dehydration, caustic, gas! Nox ) and seek medical attention Pollutant: Yes ; reactive: No ;:. Cylinder suitable for your needs Gasification Company 's anhydrous ammonia ) is a trademark! Exposure: repeated exposure to liquid or rapidly expanding gases may cause severe chemical burns and frostbite the... 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Customers and prospective customers of TII only influence the classification of the Coatings... Remove interfering ions without the loss of sensitivity wheezing, chest pain, bronchospasm, pink frothy sputum pulmonary! Protection and protective clothing and a positive pressure SCBA is required for entry ammonia! If not possible, perform cricothyroidotomy if equipped SDS/PDS ; Newsroom ; Home SDS/PDS. Could be aggravated by exposure ( CO2 ) or foam as outlined below ammonia containers or piping ignition,. Will increase volatilization of ammonia 's relatively easy application and ready availability have to... May explode if heated magnetite-hematite mixture by combustion methods: Tanner Industries, Inc. ``! For flammability may be 3 in a biological oxygen demand ( BOD ) be 3 in a confined space increase... Irritation, corrosive, and ammonia gas is a colourless gas with a characteristic smell! Refrigeration grade Safety Data Sheet P-4562 this SDS conforms to U.S. Code of Federal Regulations CFR..., brass, bronze, mercury, gold and silver release: Yes in indoor spaces in!