One cubic foot of anhydrous ammonia in a liquid state pro-duces 855 cubic Note that these guidelines are not comprehensive, and all individuals working with anhydrous ammonia should receive training in the proper response to exposure emergencies. NH3 is a clear, colorless gas and has a very characteristic odor. Anhydrous Ammonia (NH 3) Anhydrous Ammonia is a product with the chemical formula NH 3, in either a liquid or gas state, that is stored, transported or contained in a pressure vessel under pressure and is used as a fertilizer. The human body is 50 to 75 percent water including skin, eyes, nose, throat and lungs. Workers in all industries should know that, despite its common usage, ammonia Do not use dented or damaged tanks until they have been checked by an authorized inspector and necessary repairs are completed. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz��������������������������������������������������������������������������� It is stored under pressure to prevent vaporiza-tion so a large volume can be available for use. Ammonia ammonia; anhydrous ammonia Gas. Ammonia, Anhydrous Safety Data Sheet 302 08/31/2017 EN (English) SDS Ref. Personal Protective Equipment Employees who work regularly with anhydrous ammonia and are subject to overexposure either to the liquid or the vapor should be provided with proper safety equipment. It has a unique odor that can be detected at a low concentration of 5 ppm. Seek medical attention immediately and inform medical staff of the exposure to anhydrous ammonia so that they will not treat the wounds with oils or ointments that can intensify the damage. 2 Anhydrous Ammonia Safety General The term “ammonia” in this booklet means “anhydrous ammonia” which has the molecular formula NH3.Ammonia is formed by the combination of nitrogen and hydrogen at high temperature and A tractor can tow two tanks, but a truck can tow only one tank at a time. PPE should include ventless goggles or a full-face shield, rubber gloves with long cuffs that can be rolled to catch drips, and a long-sleeved shirt. Anhydrous ammonia – used in manufacturing, refrigeration and agriculture – is a pungent, colorless and toxic gas or liquid that, when concentrated, is corrosive to human tissue upon contact, according to NIOSH. The concentration in fertilizer is approximately 1,000,000 ppm, but even brief exposure to a concentration of 2,500 to 6,500 ppm can result in death. $4�%�&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz�������������������������������������������������������������������������� ? This work is supported by the USDA National Institute of Food and Agriculture, New Technologies for Ag Extension project. John Nowatzki, NDSU Extension agricultural machine systems … Anhydrous ammonia inhalation incidents are typically severe because the victim’s throat can swell shut, causing suffocation. Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. When anhydrous ammonia comes in contact with human tissue it is extremely destructive and can cause severe chemical burns. (2002) Ohio State University Extension Agricultural Tailgate Safety Training. The first-response treatment for anhydrous ammonia exposure is to flush the exposed area (skin, nose, throat, eyes, and so on) with clean water for a minimum of 15 minutes. Preventing Ammonia Burns and How to Treat Them, Michigan State … [29 CFR 1910.120(g)(3), 29 CFR 1910.132] Agricultural Safety and Health). A self-contained breathing apparatus (SCBA) and protective clothing are necessary to remove a person from a continuous stream. Iowa Fertilizer and Chemical Association. �� � } !1AQa"q2���#B��R��$3br� “As liquid Remember to bleed pressurized anhydrous ammonia from the hose before connecting or disconnecting the hose. Ammonia is also flammable at concentrations Anhydrous Ammonia Safety Training The Fertilizer Institute in partnership with TRANSCAER SM created anhydrous ammonia safety training videos and documents. ���� JFIF ` ` �� C �� C�� ~�" �� Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). 79 0 obj Paint the tank with reflective white paint to decrease excessive pressure buildup that can occur when the tank is heated from direct sunlight. Therefore, real-time monitors are necessary to allow continuous determination of the Personal Protective Equipment (PPE) necessary to provide proper protection from ammonia. Retrieved from http://nasdonline.org/1794/d001750/towing-anhydrous-ammonia-tanks.html. http://www.safetyvideos.com/Anhydrous_Ammonia_Safety_Training_Video_p/hz0802.htm This video details the hazardous associated with anhydrous ammonia. %���� Each person working with anhydrous ammonia should carry a 6 to 8 fl. It’s a highly hazardous chemical gas that is both toxic and flammable. Because contact lenses can trap the gas and become fused to the eye, it is recommended that individuals not wear contact lenses while working with anhydrous ammonia. It is important for all individuals working with this type of fertilizer to understand the potential risks, necessary safety precautions, and proper response in the event of accidental contact. Transportation. Anhydrous Ammonia (NH3) Safety COVID-19 Update: Information for customers, suppliers, and employees. The odor of NH3 is the strongest safety feature of the chemical. This six-part course is designed for emergency responders in communities where anhydrous ammonia is manufactured, stored, or shipped. Workers in all industries should know that, despite its common usage, ammonia poses health risks and hazards that require proper use of personal protective equipment (PPE) and safe use and handling procedures. Ammonia can be mixed with water and sold as ammonium hydroxide, or used in compressed gas as anhydrous ammonia (meaning without water). A Department of Transportation (DOT) placard number 1005 for nonflammable gas should be placed on the front, back, and sides of the tank. When exposed to humans or animals, it can be suffocating in sufficient concentration, and can cause serious medical problems even at relatively low concentrations. Anhydrous ammonia inhalation incidents are typically severe because the victim’s throat can swell shut, causing suffocation. Anhydrous ammonia is used as a refrigerant in many industrial facilities, including food processing plants. <>stream Exposure to 300 parts per million (ppm) is immediately dangerous to life and health. Doss, H.J., 1998. The transfer hose should be replaced five years from the date of manufacture. Storage. It is essential that all workers who use anhydrous ammonia wear the appropriate personal protective equipment (PPE), be equipped with necessary response supplies, and know how to respond in an emergency. Nonrubber gloves made of ammonia-proof material are acceptable. Anhydrous Ammonia Safety, 1990. National Land-Grant Research and Extension Agenda for Agricultural Safety and Health: National Agenda for Action, Recursos en Español sobre Seguridad y Salud Agrícola, A Guide to Teaching Safe Tractor Operation, http://www.extension.org/pages/63196/anhydrous-ammonia-safety, https://store.extension.iastate.edu/ItemDetail.aspx?ProductID=4989, http://nasdonline.org/1731/d001719/safe-handling-of-anhydrous-ammonia-nh…, http://nasdonline.org/1794/d001750/towing-anhydrous-ammonia-tanks.html, farm safety health farm safety and health, national ag safety health reference documents and visuals, national ag safety health reference documents visuals, national ag safety health resource organizations. oz. Despite all safety measures, loss of containment can occur as happened in the incident in Potchefstroom, South Africa, in 1973 where a horizontal cylindrical tank released 38 metric tons of anhydrous ammonia. ANHYDROUS AMMONIA is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. Eye-wash and safety-shower should be available in immediate vicinity. endobj Protective measures are needed to ensure the safety of those working with NH3 and any people who live, work, or otherwise are near NH3. Safety Data Sheet Anhydrous ammonia Issue date: 05/11/2010 Supersedes: Revision date: 17/07/2020 Version: 3.0 SDS reference: SDS-002-CLP Air Liquide UK Ltd. Station Road Coleshill B46 1JY Birmingham United Retrieved from https://store.extension.iastate.edu/ItemDetail.aspx?ProductID=4989. Identification::: Chemical name :ammonia Supplier's details : Ammonia Product use 6 0 obj This material is subject to Process Safety Management requirements of 29 CFR 1910.119 if maintained on-site, including storage / process, in quantities of 10,000 pounds (ammonia, anhydrous) or greater. Experts from around the world will discuss the latest advances related to the safe production and use of ammonia, case studies Anhydrous ammonia is a liquid when compressed or cooled. If you find a person who is in a continuous stream of anhydrous ammonia, contact your local emergency service responders or 911. Department of Occupational Safety and Health Malaysia, Guidelines On The Control Of Chemicals Hazardous to Health U.S. Occupational Safety and Health Administration, Occupational Safety and Retrieved from http://www.extension.org/pages/63196/anhydrous-ammonia-safety. 14 Upon catastrophic rupture of a tank and release, the ammonia will be spilled partly as vapor and partly as a boiling liquid, which will spread over the ground whilst evaporating. When filling your anhydrous ammonia tank, do not fill it more than 85% full, and always disconnect the fill hose before moving the tank. Do not store other materials, such as propane or liquefied petroleum gas, in a tank that has been used to store anhydrous ammonia. Anhydrous ammonia is a strong alkali that, when dissolved in water, readily reacts with copper, zinc, brass, and other alloys. Incidents can occur when anhydrous ammonia escapes from transfer hoses or valves, equipment malfunctions and sprays anhydrous ammonia in multiple directions, hoses pull apart during transportation or application, and so on. Anhydrous Ammonia is a chemical compound that is classified as toxic, dangerous for the environment, flammable (in gas form), and can be explosive when mixed with air. Iowa State University Extension and Outreach. : 302 4/17 Symptoms/injuries after ingestion : Ingestion is an unlikely route of exposure for a gas. Anhydrous means "without water." Ammonia is considered a high health hazard because it is corrosive to the skin, eyes, and lungs. Regulations and codes regarding towing of anhydrous ammonia and signage may vary, so be familiar with and obey the regulations in your state. ammonia detector ammonia monitor ammonia gas detectors However, anhydrous ammonia is toxic and explosive, so pressure containers are required for transport and storage. Safety. Anhydrous ammonia safety 1. If you use a vehicle to transport anhydrous ammonia, you must carry a 5 gal. Easy online ordering for the ones who get it done along with 24/7 customer service, free technical support & more. squeeze bottle of water at all times for rapid response to an emergency. Anhydrous Ammonia Nurse Tank Safety The most commonly-used nitrogen fertilizer source in North Dakota, anhydrous ammonia plays a vital role in the production of high-quality food and feed. container of clean water. Anhydrous ammonia is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. Anhydrous Ammonia: Safety & the Farmer - TDG Certification Successful trainees receive: TDG (Transportation of Dangerous Goods) certificate valid for three (3) years from the date signed confirming that they are qualified to transport and handle anhydrous ammonia (Class 2.3 (8)) in a farm setting. Anhydrous ammonia (NH3) is a nitrogen crop fertilizer that can cause severe chemical burns; frostbite to the eyes, skin, and respiratory tract; and death. (2002) Ohio State University Extension. Safety operation of anhydrous ammonia equipment Treating straw with anhydrous ammonia has many advantages, such as high efficiency, low cost, simplicity of operation and elimination of parasite eggs and weed seeds. AMMONIA ANHYDROUS CAS No. When transporting anhydrous ammonia, be sure to adhere to the following precautions and safety rules: Schwab, C., Hanna, M., & Miller, L. (2008) Anhydrous ammonia safety: Play it safe with anhydrous ammonia. Anhydrous ammonia is transported under pressure as a liquid, so all equipment used for transport must be designed for use under high pressure to avoid ruptures or breaks. Rescue workers will contact a hazardous materials (HAZMAT) disposal team if HAZMAT services are needed at the scene. Don't miss the 64th Annual Safety in Ammonia Plants and Related Facilities Symposium. Because NH 3 CONTAINS NO WATER, it is attracted to any form of moisture. Anhydrous Basics Chemical Formula is NH3 Made up of one part nitrogen (N) and three parts hydrogen (H3 ) One of the most widely used sources of nitrogen for plant growth. Searching for Anhydrous Ammonia Safety products? Retrieved from http://nasdonline.org/1731/d001719/safe-handling-of-anhydrous-ammonia-nh…. <> Typically, anhydrous ammonia is stored under pressure, but it vaporizes to a colorless gas. (2012) Farm and Ranch eXtension in Safety and Health (FReSH) Community of Practice. Anhydrous ammonia – used in manufacturing, refrigeration and agriculture – is a pungent, colorless and toxic gas or liquid that, when concentrated, is corrosive to … While NH 3 is dangerous, anhydrous ammonia also has countless uses relating to the medicinal field, functions as a cleaning agent when diluted, is commonly used as a fertilizer, and in some cases is stolen to illegally produce methamphetamine. • Anhydrous ammonia is: –classified as a dangerous good Class 2.3(8) and is a toxic inhalation hazard (TIH); –regulated by Transport Canada under the Transportation of Dangerous Goods Act and Regulations (TDGR) ��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� L� ���?_�� ���]��_��ׄ]�|h�-�.�'�Mo�WW��� vU����/�&��Y�%X'y"YQdT���=� �����W�?�:�?� 憿b���. Therefore, the only types of containers, fittings, and piping that should come in contact with anhydrous ammonia should be nongalvanized steel or iron. When vapors or liquid come in contact with a person’s eyes, blindness may occur. Remove contaminated clothing unless the clothing is frozen to the victim’s skin. Anhydrous ammonia is classified as a hazardous substance, although few problems occur when it is properly handled and applied as intended. • Anhydrous ammonia is an important nitrogen fertilizer used by farmers primarily in Western Canada. May cause burns or irritation of the linings of When vapors or liquid come in contact with a person’s eyes, blindness may occur. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. Training module: Towing anhydrous ammonia tanks. Flush the exposed area immediately to decrease injury caused by the anhydrous ammonia coming in contact with skin or clothes. (Source: Pennsylvania State University. Anhydrous ammonia (NH3) is a nitrogen crop fertilizer that can cause severe injury and even death. Anhydrous Ammonia Keys to maintaining Anhydrous Safety 2. Typically, anhydrous ammonia is stored … ANHYDROUS AMMONIA SAFETY Anhydrous means "without water."' Grainger's got your back. Anhydrous ammonia safety. In the event of an exposure emergency, the most important resource is an ample supply of clean water to begin flushing the eyes and skin. Although clean water is the ideal resource for flushing exposed areas of the body, if you do not have water available, other nontoxic liquids, such as cold coffee or orange juice, can be used. The hydrostatic relief valve should be replaced every five years. Training module: Safe handling of anhydrous ammonia (NH3). Anhydrous Ammonia Safety Since we've been discussing the use of anhydrous ammonia in the cleaning industry, as a fertilizer additive, and in manufacturing, let's … Inform the emergency medical responders about the type of incident so they can bring the proper equipment to the scene. : 7664 – 41 - 7 ... As discussed above, should be near, but outside of ammonia area. Anhydrous Ammonia Safety Meeting Online workshop North Dakota State University Extension’s Stark-Billings County office is hosting Tuesday, April 7, at 6 p.m. Mountain time. While Ammonia’s distinctive smell makes it relatively easy to initially identify, accurate calibration is needed to ensure life safety. If exposed to NH 3-- immediately flush the exposed body area(s) with water for at %PDF-1.7 Because NH3 contains no water, it is attracted to any form of moist Anhydrous Ammonia MSDS. Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. Allow only certified welders to perform welding on the tank. Anhydrous ammonia (NH3) is a hazardous chemical and must be dealt with carefully. �� � w !1AQaq"2�B���� #3R�br� Contaminated clothing unless the clothing is frozen to the scene HAZMAT ) disposal team if HAZMAT services needed! 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